Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate

The asymmetric unit of the title compound, [Ni(C(10)H(8)N(2))(3)][Mo(6)O(19)], consists of one complex [(Ni(C(10)H(8)N(2))(3)](2+) cation and one Lindqvist-type [Mo(6)O(19)](2−) polyanion. The Ni(2+) ion is in a distorted octa­hedral coordination by six N atoms from three chelating 2,2′-bipyridine l...

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Detalles Bibliográficos
Autores principales: Fan, Liming, Wei, Peihai, Pang, Shuming, Zhang, Xiutang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007854/
https://www.ncbi.nlm.nih.gov/pubmed/21588523
http://dx.doi.org/10.1107/S1600536810032058
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author Fan, Liming
Wei, Peihai
Pang, Shuming
Zhang, Xiutang
author_facet Fan, Liming
Wei, Peihai
Pang, Shuming
Zhang, Xiutang
author_sort Fan, Liming
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(10)H(8)N(2))(3)][Mo(6)O(19)], consists of one complex [(Ni(C(10)H(8)N(2))(3)](2+) cation and one Lindqvist-type [Mo(6)O(19)](2−) polyanion. The Ni(2+) ion is in a distorted octa­hedral coordination by six N atoms from three chelating 2,2′-bipyridine ligands. The Lindqvist-type anion exhibits the characteristic Mo—O bond-length distribution, with the shortest bonds being the Mo—O(terminal) bonds [mean = 1.679 (2) Å] and the longest being those to the central O atom [mean = 2.318 (7) Å]. A number of C—H⋯O inter­actions contribute to the crystal packing.
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spelling pubmed-30078542010-12-30 Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate Fan, Liming Wei, Peihai Pang, Shuming Zhang, Xiutang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(10)H(8)N(2))(3)][Mo(6)O(19)], consists of one complex [(Ni(C(10)H(8)N(2))(3)](2+) cation and one Lindqvist-type [Mo(6)O(19)](2−) polyanion. The Ni(2+) ion is in a distorted octa­hedral coordination by six N atoms from three chelating 2,2′-bipyridine ligands. The Lindqvist-type anion exhibits the characteristic Mo—O bond-length distribution, with the shortest bonds being the Mo—O(terminal) bonds [mean = 1.679 (2) Å] and the longest being those to the central O atom [mean = 2.318 (7) Å]. A number of C—H⋯O inter­actions contribute to the crystal packing. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007854/ /pubmed/21588523 http://dx.doi.org/10.1107/S1600536810032058 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Liming
Wei, Peihai
Pang, Shuming
Zhang, Xiutang
Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title_full Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title_fullStr Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title_full_unstemmed Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title_short Tris(2,2′-bipyridine)­nickel(II) hexa­molybdate
title_sort tris(2,2′-bipyridine)­nickel(ii) hexa­molybdate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007854/
https://www.ncbi.nlm.nih.gov/pubmed/21588523
http://dx.doi.org/10.1107/S1600536810032058
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AT zhangxiutang tris22bipyridinenickeliihexamolybdate

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