N-(3-Methyl­phen­yl)pyrimidin-2-amine

Two independent mol­ecules comprise the asymmetric unit in the title compound, C(11)H(11)N(3). These differ in terms of the relative orientations of the aromatic rings: the first is somewhat twisted, while the second is approximately planar [dihedral angles between the pyrimidine and phenyl rings =...

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Autores principales: Badaruddin, Edura, Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007855/
https://www.ncbi.nlm.nih.gov/pubmed/21588767
http://dx.doi.org/10.1107/S1600536810033301
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author Badaruddin, Edura
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Badaruddin, Edura
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Badaruddin, Edura
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit in the title compound, C(11)H(11)N(3). These differ in terms of the relative orientations of the aromatic rings: the first is somewhat twisted, while the second is approximately planar [dihedral angles between the pyrimidine and phenyl rings = 39.00 (8) and 4.59 (11)°]. The mol­ecules also form distinct patterns in their hydrogen bonding. The first independent mol­ecule forms centrosymmetric dimers featuring an eight-membered {HNCN}(2) synthon. The second independent mol­ecule forms an N—H⋯N hydrogen bond with the other pyrimidine N atom of the first mol­ecule. Thereby, tetra­meric aggregates are formed. These associate via C—H⋯N and C—H⋯π inter­actions, consolidating the crystal packing.
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spelling pubmed-30078552010-12-30 N-(3-Methyl­phen­yl)pyrimidin-2-amine Badaruddin, Edura Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent mol­ecules comprise the asymmetric unit in the title compound, C(11)H(11)N(3). These differ in terms of the relative orientations of the aromatic rings: the first is somewhat twisted, while the second is approximately planar [dihedral angles between the pyrimidine and phenyl rings = 39.00 (8) and 4.59 (11)°]. The mol­ecules also form distinct patterns in their hydrogen bonding. The first independent mol­ecule forms centrosymmetric dimers featuring an eight-membered {HNCN}(2) synthon. The second independent mol­ecule forms an N—H⋯N hydrogen bond with the other pyrimidine N atom of the first mol­ecule. Thereby, tetra­meric aggregates are formed. These associate via C—H⋯N and C—H⋯π inter­actions, consolidating the crystal packing. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007855/ /pubmed/21588767 http://dx.doi.org/10.1107/S1600536810033301 Text en © Badaruddin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Badaruddin, Edura
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
N-(3-Methyl­phen­yl)pyrimidin-2-amine
title N-(3-Methyl­phen­yl)pyrimidin-2-amine
title_full N-(3-Methyl­phen­yl)pyrimidin-2-amine
title_fullStr N-(3-Methyl­phen­yl)pyrimidin-2-amine
title_full_unstemmed N-(3-Methyl­phen­yl)pyrimidin-2-amine
title_short N-(3-Methyl­phen­yl)pyrimidin-2-amine
title_sort n-(3-methyl­phen­yl)pyrimidin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007855/
https://www.ncbi.nlm.nih.gov/pubmed/21588767
http://dx.doi.org/10.1107/S1600536810033301
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AT tiekinkedwardrt n3methylphenylpyrimidin2amine

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