2-[(4-Chlorobenzyl)iminomethyl]phenol

The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chloro­benzyl­amine and salicyl­aldehyde. The mol­ecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intra­molecu...

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Detalles Bibliográficos
Autores principales: Phurat, Chuttree, Teerawatananond, Thapong, Muangsin, Nongnuj
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007859/
https://www.ncbi.nlm.nih.gov/pubmed/21588659
http://dx.doi.org/10.1107/S1600536810031508
Descripción
Sumario:The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chloro­benzyl­amine and salicyl­aldehyde. The mol­ecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intra­molecular N—H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C—H⋯O contacts are observed.

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