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2-[(4-Chlorobenzyl)iminomethyl]phenol
The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chlorobenzylamine and salicylaldehyde. The molecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intramolecu...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007859/ https://www.ncbi.nlm.nih.gov/pubmed/21588659 http://dx.doi.org/10.1107/S1600536810031508 |
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author | Phurat, Chuttree Teerawatananond, Thapong Muangsin, Nongnuj |
author_facet | Phurat, Chuttree Teerawatananond, Thapong Muangsin, Nongnuj |
author_sort | Phurat, Chuttree |
collection | PubMed |
description | The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chlorobenzylamine and salicylaldehyde. The molecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intramolecular N—H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C—H⋯O contacts are observed. |
format | Text |
id | pubmed-3007859 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078592010-12-30 2-[(4-Chlorobenzyl)iminomethyl]phenol Phurat, Chuttree Teerawatananond, Thapong Muangsin, Nongnuj Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chlorobenzylamine and salicylaldehyde. The molecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intramolecular N—H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C—H⋯O contacts are observed. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007859/ /pubmed/21588659 http://dx.doi.org/10.1107/S1600536810031508 Text en © Phurat et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Phurat, Chuttree Teerawatananond, Thapong Muangsin, Nongnuj 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title | 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title_full | 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title_fullStr | 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title_full_unstemmed | 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title_short | 2-[(4-Chlorobenzyl)iminomethyl]phenol |
title_sort | 2-[(4-chlorobenzyl)iminomethyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007859/ https://www.ncbi.nlm.nih.gov/pubmed/21588659 http://dx.doi.org/10.1107/S1600536810031508 |
work_keys_str_mv | AT phuratchuttree 24chlorobenzyliminomethylphenol AT teerawatananondthapong 24chlorobenzyliminomethylphenol AT muangsinnongnuj 24chlorobenzyliminomethylphenol |