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4-Hydroxy-3-(3-methoxybenzoyl)-2-[(3-methoxybenzoyl)methyl]-2H-1,2-benzothiazine 1,1-dioxide
In the title compound, C(25)H(21)NO(7)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) an...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007862/ https://www.ncbi.nlm.nih.gov/pubmed/21588662 http://dx.doi.org/10.1107/S1600536810031673 |
Sumario: | In the title compound, C(25)H(21)NO(7)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) and ϕ = 34.3 (3)°. The structure is devoid of any classical hydrogen bonds. However, intramolecular C—H⋯N and O—H⋯O hydrogen bonds result in six-membered rings and intermolecular C—H⋯O interactions stabilize the crystal structure. |
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