4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide

In the title compound, C(25)H(21)NO(7)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) an...

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Autores principales: Gul, Salman, Siddiqui, Hamid Latif, Ahmad, Matloob, Nisar, Muhammad, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007862/
https://www.ncbi.nlm.nih.gov/pubmed/21588662
http://dx.doi.org/10.1107/S1600536810031673
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author Gul, Salman
Siddiqui, Hamid Latif
Ahmad, Matloob
Nisar, Muhammad
Parvez, Masood
author_facet Gul, Salman
Siddiqui, Hamid Latif
Ahmad, Matloob
Nisar, Muhammad
Parvez, Masood
author_sort Gul, Salman
collection PubMed
description In the title compound, C(25)H(21)NO(7)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) and ϕ = 34.3 (3)°. The structure is devoid of any classical hydrogen bonds. However, intra­molecular C—H⋯N and O—H⋯O hydrogen bonds result in six-membered rings and inter­molecular C—H⋯O inter­actions stabilize the crystal structure.
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spelling pubmed-30078622010-12-30 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide Gul, Salman Siddiqui, Hamid Latif Ahmad, Matloob Nisar, Muhammad Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(21)NO(7)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by −0.284 (3) and 0.411 (3) Å, respectively, from the plane formed by the remaining ring atoms; the puckering parameters are: Q = 0.4576 (13) Å, θ = 58.6 (2) and ϕ = 34.3 (3)°. The structure is devoid of any classical hydrogen bonds. However, intra­molecular C—H⋯N and O—H⋯O hydrogen bonds result in six-membered rings and inter­molecular C—H⋯O inter­actions stabilize the crystal structure. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007862/ /pubmed/21588662 http://dx.doi.org/10.1107/S1600536810031673 Text en © Gul et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gul, Salman
Siddiqui, Hamid Latif
Ahmad, Matloob
Nisar, Muhammad
Parvez, Masood
4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title_full 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title_fullStr 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title_full_unstemmed 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title_short 4-Hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2H-1,2-benzothia­zine 1,1-dioxide
title_sort 4-hy­droxy-3-(3-meth­oxybenzoyl)-2-[(3-meth­oxybenzoyl)methyl]-2h-1,2-benzothia­zine 1,1-dioxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007862/
https://www.ncbi.nlm.nih.gov/pubmed/21588662
http://dx.doi.org/10.1107/S1600536810031673
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