9β-Hy­droxy-1β,10α-ep­oxy­parthenolide

The title compound, C(15)H(20)O(5) (systematic name: 5-hydroxy-1a,4a-dimethyl-7-methyleneperhydrodioxireno[5,6:9,10]cyclo­deca[1,2-b]furan-8-one), was obtained by the reaction of 3-chloro­perbenzoic acid with 9β-hy­droxy­parthenolide. The five-membered ring adopts a twist conformation, whereas the t...

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Detalles Bibliográficos
Autores principales: Moumou, Mohamed, Akssira, Mohamed, El Ammari, Lahcen, Benharref, Ahmed, Berraho, Moha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007864/
https://www.ncbi.nlm.nih.gov/pubmed/21588728
http://dx.doi.org/10.1107/S1600536810033404
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author Moumou, Mohamed
Akssira, Mohamed
El Ammari, Lahcen
Benharref, Ahmed
Berraho, Moha
author_facet Moumou, Mohamed
Akssira, Mohamed
El Ammari, Lahcen
Benharref, Ahmed
Berraho, Moha
author_sort Moumou, Mohamed
collection PubMed
description The title compound, C(15)H(20)O(5) (systematic name: 5-hydroxy-1a,4a-dimethyl-7-methyleneperhydrodioxireno[5,6:9,10]cyclo­deca[1,2-b]furan-8-one), was obtained by the reaction of 3-chloro­perbenzoic acid with 9β-hy­droxy­parthenolide. The five-membered ring adopts a twist conformation, whereas the ten-membered ring displays an approximate chair–chair conformation. In the crystal structure, mol­ecules are linked into chains propagating along the b axis by inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-30078642010-12-30 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide Moumou, Mohamed Akssira, Mohamed El Ammari, Lahcen Benharref, Ahmed Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)O(5) (systematic name: 5-hydroxy-1a,4a-dimethyl-7-methyleneperhydrodioxireno[5,6:9,10]cyclo­deca[1,2-b]furan-8-one), was obtained by the reaction of 3-chloro­perbenzoic acid with 9β-hy­droxy­parthenolide. The five-membered ring adopts a twist conformation, whereas the ten-membered ring displays an approximate chair–chair conformation. In the crystal structure, mol­ecules are linked into chains propagating along the b axis by inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007864/ /pubmed/21588728 http://dx.doi.org/10.1107/S1600536810033404 Text en © Moumou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moumou, Mohamed
Akssira, Mohamed
El Ammari, Lahcen
Benharref, Ahmed
Berraho, Moha
9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title_full 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title_fullStr 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title_full_unstemmed 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title_short 9β-Hy­droxy-1β,10α-ep­oxy­parthenolide
title_sort 9β-hy­droxy-1β,10α-ep­oxy­parthenolide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007864/
https://www.ncbi.nlm.nih.gov/pubmed/21588728
http://dx.doi.org/10.1107/S1600536810033404
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AT benharrefahmed 9bhydroxy1b10aepoxyparthenolide
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