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Poly[(μ(3)-5-aminoisophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2) N:N′]cobalt(II)]
In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelat...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007865/ https://www.ncbi.nlm.nih.gov/pubmed/21588491 http://dx.doi.org/10.1107/S1600536810030710 |
Sumario: | In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the other carboxylate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis(4-pyridyl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis(4-pyridyl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H⋯O hydrogen bonding and N—H⋯π interactions are observed in the crystal structure. A void of 69 (5) Å(3) is present in the crystal structure, but no solvent molecule can be located reasonably. |
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