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Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]

In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octa­hedral coordination geometry, formed by three 5-amino­isophthalate dianions and two 1,2-bis­(4-pyrid­yl)ethane ligands. One carboxyl­ate group of the 5-amino­isophthalate dianion chelat...

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Autores principales: Lush, Shie Fu, Shen, Fwu Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007865/
https://www.ncbi.nlm.nih.gov/pubmed/21588491
http://dx.doi.org/10.1107/S1600536810030710
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author Lush, Shie Fu
Shen, Fwu Ming
author_facet Lush, Shie Fu
Shen, Fwu Ming
author_sort Lush, Shie Fu
collection PubMed
description In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octa­hedral coordination geometry, formed by three 5-amino­isophthalate dianions and two 1,2-bis­(4-pyrid­yl)ethane ligands. One carboxyl­ate group of the 5-amino­isophthalate dianion chelates a Co cation and the other carboxyl­ate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis­(4-pyrid­yl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis­(4-pyrid­yl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H⋯O hydrogen bonding and N—H⋯π inter­actions are observed in the crystal structure. A void of 69 (5) Å(3) is present in the crystal structure, but no solvent mol­ecule can be located reasonably.
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spelling pubmed-30078652010-12-30 Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)] Lush, Shie Fu Shen, Fwu Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octa­hedral coordination geometry, formed by three 5-amino­isophthalate dianions and two 1,2-bis­(4-pyrid­yl)ethane ligands. One carboxyl­ate group of the 5-amino­isophthalate dianion chelates a Co cation and the other carboxyl­ate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis­(4-pyrid­yl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis­(4-pyrid­yl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H⋯O hydrogen bonding and N—H⋯π inter­actions are observed in the crystal structure. A void of 69 (5) Å(3) is present in the crystal structure, but no solvent mol­ecule can be located reasonably. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007865/ /pubmed/21588491 http://dx.doi.org/10.1107/S1600536810030710 Text en © Lush and Shen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lush, Shie Fu
Shen, Fwu Ming
Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title_full Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title_fullStr Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title_full_unstemmed Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title_short Poly[(μ(3)-5-amino­isophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) N:N′]cobalt(II)]
title_sort poly[(μ(3)-5-amino­isophthalato-κ(4) o,o′:o′′:o′′′)[μ(2)-1,2-bis­(4-pyrid­yl)ethane-κ(2) n:n′]cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007865/
https://www.ncbi.nlm.nih.gov/pubmed/21588491
http://dx.doi.org/10.1107/S1600536810030710
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