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Poly[(μ(3)-5-aminoisophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2) N:N′]cobalt(II)]
In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelat...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007865/ https://www.ncbi.nlm.nih.gov/pubmed/21588491 http://dx.doi.org/10.1107/S1600536810030710 |
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author | Lush, Shie Fu Shen, Fwu Ming |
author_facet | Lush, Shie Fu Shen, Fwu Ming |
author_sort | Lush, Shie Fu |
collection | PubMed |
description | In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the other carboxylate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis(4-pyridyl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis(4-pyridyl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H⋯O hydrogen bonding and N—H⋯π interactions are observed in the crystal structure. A void of 69 (5) Å(3) is present in the crystal structure, but no solvent molecule can be located reasonably. |
format | Text |
id | pubmed-3007865 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078652010-12-30 Poly[(μ(3)-5-aminoisophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2) N:N′]cobalt(II)] Lush, Shie Fu Shen, Fwu Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(5)NO(4))(C(12)H(12)N(2))](n), the Co(II) ion presents a distorted CoO(4)N(2) octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the other carboxylate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis(4-pyridyl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis(4-pyridyl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H⋯O hydrogen bonding and N—H⋯π interactions are observed in the crystal structure. A void of 69 (5) Å(3) is present in the crystal structure, but no solvent molecule can be located reasonably. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007865/ /pubmed/21588491 http://dx.doi.org/10.1107/S1600536810030710 Text en © Lush and Shen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lush, Shie Fu Shen, Fwu Ming Poly[(μ(3)-5-aminoisophthalato-κ(4) O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2) N:N′]cobalt(II)] |
title | Poly[(μ(3)-5-aminoisophthalato-κ(4)
O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
N:N′]cobalt(II)] |
title_full | Poly[(μ(3)-5-aminoisophthalato-κ(4)
O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
N:N′]cobalt(II)] |
title_fullStr | Poly[(μ(3)-5-aminoisophthalato-κ(4)
O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
N:N′]cobalt(II)] |
title_full_unstemmed | Poly[(μ(3)-5-aminoisophthalato-κ(4)
O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
N:N′]cobalt(II)] |
title_short | Poly[(μ(3)-5-aminoisophthalato-κ(4)
O,O′:O′′:O′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
N:N′]cobalt(II)] |
title_sort | poly[(μ(3)-5-aminoisophthalato-κ(4)
o,o′:o′′:o′′′)[μ(2)-1,2-bis(4-pyridyl)ethane-κ(2)
n:n′]cobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007865/ https://www.ncbi.nlm.nih.gov/pubmed/21588491 http://dx.doi.org/10.1107/S1600536810030710 |
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