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2-(Pyrimidin-2-yloxy)phenol
The pyrimidine and benzene rings in the title compound, C(10)H(8)N(2)O(2), form a dihedral angle of 71.03 (7)°, with the roughly orthogonal benzene ring being folded towards one of the pyrimidine N atoms. In the crystal, pairs of O—H⋯N hydrogen bonds connect molecules related by twofold symmetry in...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007867/ https://www.ncbi.nlm.nih.gov/pubmed/21588583 http://dx.doi.org/10.1107/S1600536810030448 |
Sumario: | The pyrimidine and benzene rings in the title compound, C(10)H(8)N(2)O(2), form a dihedral angle of 71.03 (7)°, with the roughly orthogonal benzene ring being folded towards one of the pyrimidine N atoms. In the crystal, pairs of O—H⋯N hydrogen bonds connect molecules related by twofold symmetry into dimeric aggregates. These associate into a supramolecular chain propagating along the b axis by way of C—H⋯π contacts. The chains are cross-linked by π–π interactions that occur between pyrimidine rings [ring centroid–centroid distances = 3.5393 (9) and 3.5697 (9) Å]. |
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