Cargando…
Di-μ-sulfato-κ(4) O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate
In the title centrosymmetric dinuclear compound, [Mn(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Mn(II) atom is octahedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007874/ https://www.ncbi.nlm.nih.gov/pubmed/21588521 http://dx.doi.org/10.1107/S1600536810031909 |
_version_ | 1782194448299458560 |
---|---|
author | Yang, Ming-Xing Lin, Shen Chen, Li-Juan Chen, Xiao-Hua |
author_facet | Yang, Ming-Xing Lin, Shen Chen, Li-Juan Chen, Xiao-Hua |
author_sort | Yang, Ming-Xing |
collection | PubMed |
description | In the title centrosymmetric dinuclear compound, [Mn(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Mn(II) atom is octahedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In the crystal structure, the complex molecules and the uncoodinated water molecules are connected by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. A π–π stacking interaction between the pyridyl ring of the ip ligand and the benzene ring of the neighboring ligand [centroid–centroid distance = 3.579 (2) Å] is also observed. |
format | Text |
id | pubmed-3007874 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078742010-12-30 Di-μ-sulfato-κ(4) O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate Yang, Ming-Xing Lin, Shen Chen, Li-Juan Chen, Xiao-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear compound, [Mn(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Mn(II) atom is octahedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In the crystal structure, the complex molecules and the uncoodinated water molecules are connected by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. A π–π stacking interaction between the pyridyl ring of the ip ligand and the benzene ring of the neighboring ligand [centroid–centroid distance = 3.579 (2) Å] is also observed. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007874/ /pubmed/21588521 http://dx.doi.org/10.1107/S1600536810031909 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Ming-Xing Lin, Shen Chen, Li-Juan Chen, Xiao-Hua Di-μ-sulfato-κ(4) O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title | Di-μ-sulfato-κ(4)
O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title_full | Di-μ-sulfato-κ(4)
O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title_fullStr | Di-μ-sulfato-κ(4)
O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title_full_unstemmed | Di-μ-sulfato-κ(4)
O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title_short | Di-μ-sulfato-κ(4)
O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate |
title_sort | di-μ-sulfato-κ(4)
o:o′-bis[diaqua(1h-imidazo[4,5-f][1,10]phenanthroline)manganese(ii)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007874/ https://www.ncbi.nlm.nih.gov/pubmed/21588521 http://dx.doi.org/10.1107/S1600536810031909 |
work_keys_str_mv | AT yangmingxing dimsulfatok4oobisdiaqua1himidazo45f110phenanthrolinemanganeseiidihydrate AT linshen dimsulfatok4oobisdiaqua1himidazo45f110phenanthrolinemanganeseiidihydrate AT chenlijuan dimsulfatok4oobisdiaqua1himidazo45f110phenanthrolinemanganeseiidihydrate AT chenxiaohua dimsulfatok4oobisdiaqua1himidazo45f110phenanthrolinemanganeseiidihydrate |