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A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate]
The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydrothermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distor...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007876/ https://www.ncbi.nlm.nih.gov/pubmed/21588488 http://dx.doi.org/10.1107/S160053681003240X |
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author | Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen |
author_facet | Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen |
author_sort | Assani, Abderrazzak |
collection | PubMed |
description | The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydrothermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octahedral. The ethylenediammonium cation and the disordered water molecule (site-occupation factors = 0.7:0.3) ensure the cohesion of the structure via N—H⋯O and O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3007876 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078762010-12-30 A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(2)H(10)N(2))[In(HPO(4))(2)(OH)]·H(2)O, was synthesized under hydrothermal conditions. The structure of this hybrid compound consists of isolated inorganic chains with composition (∞)[In(HPO(4))(4/2)(OH)(2/2)] running along [010]. The coordination of the In(III) atom is distorted octahedral. The ethylenediammonium cation and the disordered water molecule (site-occupation factors = 0.7:0.3) ensure the cohesion of the structure via N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007876/ /pubmed/21588488 http://dx.doi.org/10.1107/S160053681003240X Text en © Assani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title | A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title_full | A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title_fullStr | A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title_full_unstemmed | A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title_short | A one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(III)-di-μ-hydrogenphosphato(V)-μ-hydroxido] monohydrate] |
title_sort | one-dimensional inorganic–organic hybrid compound: catena-poly[ethylenediammonium [indate(iii)-di-μ-hydrogenphosphato(v)-μ-hydroxido] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007876/ https://www.ncbi.nlm.nih.gov/pubmed/21588488 http://dx.doi.org/10.1107/S160053681003240X |
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