(Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate

In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl­acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand....

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Autores principales: Janani, Halimeh, Rezvani, Ali Reza, Rostami-Charati, Faramarz, Makha, Mohamed, Skelton, Brian W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007884/
https://www.ncbi.nlm.nih.gov/pubmed/21588486
http://dx.doi.org/10.1107/S1600536810030163
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author Janani, Halimeh
Rezvani, Ali Reza
Rostami-Charati, Faramarz
Makha, Mohamed
Skelton, Brian W.
author_facet Janani, Halimeh
Rezvani, Ali Reza
Rostami-Charati, Faramarz
Makha, Mohamed
Skelton, Brian W.
author_sort Janani, Halimeh
collection PubMed
description In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl­acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol­ecules. There are also hydrogen bonds between both the water mol­ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction.
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spelling pubmed-30078842010-12-30 (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate Janani, Halimeh Rezvani, Ali Reza Rostami-Charati, Faramarz Makha, Mohamed Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl­acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol­ecules. There are also hydrogen bonds between both the water mol­ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3007884/ /pubmed/21588486 http://dx.doi.org/10.1107/S1600536810030163 Text en © Janani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Janani, Halimeh
Rezvani, Ali Reza
Rostami-Charati, Faramarz
Makha, Mohamed
Skelton, Brian W.
(Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title_full (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title_fullStr (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title_full_unstemmed (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title_short (Acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
title_sort (acetyl­acetonato)(dicyanamido)(1,10-phenanthroline)copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007884/
https://www.ncbi.nlm.nih.gov/pubmed/21588486
http://dx.doi.org/10.1107/S1600536810030163
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AT skeltonbrianw acetylacetonatodicyanamido110phenanthrolinecopperiidihydrate

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