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Benzoyl­dicarbon­yl(η(5)-inden­yl)ruthenium(II)

In the title mol­ecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O and C—H⋯π(arene) inter­actions. The Ru—η(5)-cyclopentadienyl centroid bon...

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Detalles Bibliográficos
Autores principales: Oudenhoven, Tracey A., Walder, Brennan J., Golen, James A., Rheingold, Arnold L., D’Acchioli, Jason S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007885/
https://www.ncbi.nlm.nih.gov/pubmed/21588552
http://dx.doi.org/10.1107/S1600536810033180
Descripción
Sumario:In the title mol­ecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O and C—H⋯π(arene) inter­actions. The Ru—η(5)-cyclopentadienyl centroid bond length is 1.946 (11) Å