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Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II)
In the title molecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯π(arene) interactions. The Ru—η(5)-cyclopentadienyl centroid bon...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007885/ https://www.ncbi.nlm.nih.gov/pubmed/21588552 http://dx.doi.org/10.1107/S1600536810033180 |
| _version_ | 1782194450922995712 |
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| author | Oudenhoven, Tracey A. Walder, Brennan J. Golen, James A. Rheingold, Arnold L. D’Acchioli, Jason S. |
| author_facet | Oudenhoven, Tracey A. Walder, Brennan J. Golen, James A. Rheingold, Arnold L. D’Acchioli, Jason S. |
| author_sort | Oudenhoven, Tracey A. |
| collection | PubMed |
| description | In the title molecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯π(arene) interactions. The Ru—η(5)-cyclopentadienyl centroid bond length is 1.946 (11) Å |
| format | Text |
| id | pubmed-3007885 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30078852010-12-30 Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) Oudenhoven, Tracey A. Walder, Brennan J. Golen, James A. Rheingold, Arnold L. D’Acchioli, Jason S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯π(arene) interactions. The Ru—η(5)-cyclopentadienyl centroid bond length is 1.946 (11) Å International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007885/ /pubmed/21588552 http://dx.doi.org/10.1107/S1600536810033180 Text en © Oudenhoven et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Oudenhoven, Tracey A. Walder, Brennan J. Golen, James A. Rheingold, Arnold L. D’Acchioli, Jason S. Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title | Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title_full | Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title_fullStr | Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title_full_unstemmed | Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title_short | Benzoyldicarbonyl(η(5)-indenyl)ruthenium(II) |
| title_sort | benzoyldicarbonyl(η(5)-indenyl)ruthenium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007885/ https://www.ncbi.nlm.nih.gov/pubmed/21588552 http://dx.doi.org/10.1107/S1600536810033180 |
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