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8-Hy­droxy­quinolinium 2-carb­oxy­acetate

In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intra­molecular O—H...

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Detalles Bibliográficos
Autores principales: Quah, Ching Kheng, Loh, Wan-Sin, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007886/
https://www.ncbi.nlm.nih.gov/pubmed/21588617
http://dx.doi.org/10.1107/S1600536810030990
Descripción
Sumario:In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. The hy­droxy group of the oxine unit makes a hydrogen bond with the one of the O atoms of the carboxyl­ate group of the 2-carb­oxy­acetate anion. Two other carboxyl­ate O atoms form R (2) (2)(7) ring motifs via inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure is consolidated by weak inter­molecular C—H⋯O inter­actions, which link the cations and anions into a three-dimensional network.