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8-Hy­droxy­quinolinium 2-carb­oxy­acetate

In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intra­molecular O—H...

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Autores principales: Quah, Ching Kheng, Loh, Wan-Sin, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007886/
https://www.ncbi.nlm.nih.gov/pubmed/21588617
http://dx.doi.org/10.1107/S1600536810030990
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author Quah, Ching Kheng
Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Quah, Ching Kheng
Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Quah, Ching Kheng
collection PubMed
description In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. The hy­droxy group of the oxine unit makes a hydrogen bond with the one of the O atoms of the carboxyl­ate group of the 2-carb­oxy­acetate anion. Two other carboxyl­ate O atoms form R (2) (2)(7) ring motifs via inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure is consolidated by weak inter­molecular C—H⋯O inter­actions, which link the cations and anions into a three-dimensional network.
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spelling pubmed-30078862010-12-30 8-Hy­droxy­quinolinium 2-carb­oxy­acetate Quah, Ching Kheng Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. The hy­droxy group of the oxine unit makes a hydrogen bond with the one of the O atoms of the carboxyl­ate group of the 2-carb­oxy­acetate anion. Two other carboxyl­ate O atoms form R (2) (2)(7) ring motifs via inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure is consolidated by weak inter­molecular C—H⋯O inter­actions, which link the cations and anions into a three-dimensional network. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007886/ /pubmed/21588617 http://dx.doi.org/10.1107/S1600536810030990 Text en © Quah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Quah, Ching Kheng
Loh, Wan-Sin
Hemamalini, Madhukar
Fun, Hoong-Kun
8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title 8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title_full 8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title_fullStr 8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title_full_unstemmed 8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title_short 8-Hy­droxy­quinolinium 2-carb­oxy­acetate
title_sort 8-hy­droxy­quinolinium 2-carb­oxy­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007886/
https://www.ncbi.nlm.nih.gov/pubmed/21588617
http://dx.doi.org/10.1107/S1600536810030990
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