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8-Hydroxyquinolinium 2-carboxyacetate
In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intramolecular O—H...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007886/ https://www.ncbi.nlm.nih.gov/pubmed/21588617 http://dx.doi.org/10.1107/S1600536810030990 |
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author | Quah, Ching Kheng Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Quah, Ching Kheng Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Quah, Ching Kheng |
collection | PubMed |
description | In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. The hydroxy group of the oxine unit makes a hydrogen bond with the one of the O atoms of the carboxylate group of the 2-carboxyacetate anion. Two other carboxylate O atoms form R (2) (2)(7) ring motifs via intermolecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure is consolidated by weak intermolecular C—H⋯O interactions, which link the cations and anions into a three-dimensional network. |
format | Text |
id | pubmed-3007886 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30078862010-12-30 8-Hydroxyquinolinium 2-carboxyacetate Quah, Ching Kheng Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(8)NO(+)·C(3)H(3)O(4) (−), the cation and anion are each essentially planar, with maximum deviations of 0.043 (1) and 0.060 (1) Å, respectively. The dihedral angle between these two planes is 2.20 (4)°. The conformation of the anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. The hydroxy group of the oxine unit makes a hydrogen bond with the one of the O atoms of the carboxylate group of the 2-carboxyacetate anion. Two other carboxylate O atoms form R (2) (2)(7) ring motifs via intermolecular C—H⋯O and N—H⋯O hydrogen bonds. The crystal structure is consolidated by weak intermolecular C—H⋯O interactions, which link the cations and anions into a three-dimensional network. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007886/ /pubmed/21588617 http://dx.doi.org/10.1107/S1600536810030990 Text en © Quah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Quah, Ching Kheng Loh, Wan-Sin Hemamalini, Madhukar Fun, Hoong-Kun 8-Hydroxyquinolinium 2-carboxyacetate |
title | 8-Hydroxyquinolinium 2-carboxyacetate |
title_full | 8-Hydroxyquinolinium 2-carboxyacetate |
title_fullStr | 8-Hydroxyquinolinium 2-carboxyacetate |
title_full_unstemmed | 8-Hydroxyquinolinium 2-carboxyacetate |
title_short | 8-Hydroxyquinolinium 2-carboxyacetate |
title_sort | 8-hydroxyquinolinium 2-carboxyacetate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007886/ https://www.ncbi.nlm.nih.gov/pubmed/21588617 http://dx.doi.org/10.1107/S1600536810030990 |
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