4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate

In the title Schiff base compound, C(12)H(11)BrN(4)O·H(2)O, the organic mol­ecule exists in an E configuration with respect to the C=N double bond. The pyrimidine ring is approximately planar, with a maximum deviation of 0.011 (2) Å, and forms a dihedral angle of 10.68 (8)° with the benzene ring. In...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Loh, Wan-Sin, Nayak, Suresh P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007892/
https://www.ncbi.nlm.nih.gov/pubmed/21588785
http://dx.doi.org/10.1107/S1600536810033283
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author Fun, Hoong-Kun
Loh, Wan-Sin
Nayak, Suresh P.
author_facet Fun, Hoong-Kun
Loh, Wan-Sin
Nayak, Suresh P.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title Schiff base compound, C(12)H(11)BrN(4)O·H(2)O, the organic mol­ecule exists in an E configuration with respect to the C=N double bond. The pyrimidine ring is approximately planar, with a maximum deviation of 0.011 (2) Å, and forms a dihedral angle of 10.68 (8)° with the benzene ring. In the crystal, inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to the ac plane.
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spelling pubmed-30078922010-12-30 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate Fun, Hoong-Kun Loh, Wan-Sin Nayak, Suresh P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base compound, C(12)H(11)BrN(4)O·H(2)O, the organic mol­ecule exists in an E configuration with respect to the C=N double bond. The pyrimidine ring is approximately planar, with a maximum deviation of 0.011 (2) Å, and forms a dihedral angle of 10.68 (8)° with the benzene ring. In the crystal, inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to the ac plane. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007892/ /pubmed/21588785 http://dx.doi.org/10.1107/S1600536810033283 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Loh, Wan-Sin
Nayak, Suresh P.
4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title_full 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title_fullStr 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title_full_unstemmed 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title_short 4-Meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
title_sort 4-meth­oxy­benzaldehyde (5-bromo­pyrimidin-2-yl)hydrazone monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007892/
https://www.ncbi.nlm.nih.gov/pubmed/21588785
http://dx.doi.org/10.1107/S1600536810033283
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AT lohwansin 4methoxybenzaldehyde5bromopyrimidin2ylhydrazonemonohydrate
AT nayaksureshp 4methoxybenzaldehyde5bromopyrimidin2ylhydrazonemonohydrate

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