{3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)

In either of the two independent mol­ecules within the asymmetric unit of the title compound, [Ni(C(16)H(15)NO(3))(C(3)H(4)N(2))], the Ni(II) atom is coordinated by the two N atoms and two O atoms in a distorted square-planar geometry. The crystal packing is stabilized by strong and weak inter­molec...

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Detalles Bibliográficos
Autores principales: Peng, Qin-Long, Zhao, Gan-Qing, Chen, Li-Hua, Xue, Ling-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007895/
https://www.ncbi.nlm.nih.gov/pubmed/21588530
http://dx.doi.org/10.1107/S1600536810032472
Descripción
Sumario:In either of the two independent mol­ecules within the asymmetric unit of the title compound, [Ni(C(16)H(15)NO(3))(C(3)H(4)N(2))], the Ni(II) atom is coordinated by the two N atoms and two O atoms in a distorted square-planar geometry. The crystal packing is stabilized by strong and weak inter­molecular C—H⋯O hydrogen bonds, as well as weak centroid–centroid π-stacking inter­actions [centroid–centroid separation = 3.526 (3) Å].

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