{3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)

In either of the two independent mol­ecules within the asymmetric unit of the title compound, [Ni(C(16)H(15)NO(3))(C(3)H(4)N(2))], the Ni(II) atom is coordinated by the two N atoms and two O atoms in a distorted square-planar geometry. The crystal packing is stabilized by strong and weak inter­molec...

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Detalles Bibliográficos
Autores principales: Peng, Qin-Long, Zhao, Gan-Qing, Chen, Li-Hua, Xue, Ling-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007895/
https://www.ncbi.nlm.nih.gov/pubmed/21588530
http://dx.doi.org/10.1107/S1600536810032472
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author Peng, Qin-Long
Zhao, Gan-Qing
Chen, Li-Hua
Xue, Ling-Wei
author_facet Peng, Qin-Long
Zhao, Gan-Qing
Chen, Li-Hua
Xue, Ling-Wei
author_sort Peng, Qin-Long
collection PubMed
description In either of the two independent mol­ecules within the asymmetric unit of the title compound, [Ni(C(16)H(15)NO(3))(C(3)H(4)N(2))], the Ni(II) atom is coordinated by the two N atoms and two O atoms in a distorted square-planar geometry. The crystal packing is stabilized by strong and weak inter­molecular C—H⋯O hydrogen bonds, as well as weak centroid–centroid π-stacking inter­actions [centroid–centroid separation = 3.526 (3) Å].
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spelling pubmed-30078952010-12-30 {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II) Peng, Qin-Long Zhao, Gan-Qing Chen, Li-Hua Xue, Ling-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In either of the two independent mol­ecules within the asymmetric unit of the title compound, [Ni(C(16)H(15)NO(3))(C(3)H(4)N(2))], the Ni(II) atom is coordinated by the two N atoms and two O atoms in a distorted square-planar geometry. The crystal packing is stabilized by strong and weak inter­molecular C—H⋯O hydrogen bonds, as well as weak centroid–centroid π-stacking inter­actions [centroid–centroid separation = 3.526 (3) Å]. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007895/ /pubmed/21588530 http://dx.doi.org/10.1107/S1600536810032472 Text en © Peng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Qin-Long
Zhao, Gan-Qing
Chen, Li-Hua
Xue, Ling-Wei
{3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title_full {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title_fullStr {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title_full_unstemmed {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title_short {3-Methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) O,N]butano­ato-κO}(1H-pyrazole-κN (2))nickel(II)
title_sort {3-methyl-2-[(1-oxido-2-naphth­yl)methyl­idene­amino-κ(2) o,n]butano­ato-κo}(1h-pyrazole-κn (2))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007895/
https://www.ncbi.nlm.nih.gov/pubmed/21588530
http://dx.doi.org/10.1107/S1600536810032472
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