A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]

The title compound, [V(2)F(2)O(4)(C(10)H(8)N)(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent V(V) atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically b...

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Detalles Bibliográficos
Autores principales: DeBurgomaster, Paul, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007897/
https://www.ncbi.nlm.nih.gov/pubmed/21588507
http://dx.doi.org/10.1107/S1600536810031302
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author DeBurgomaster, Paul
Zubieta, Jon
author_facet DeBurgomaster, Paul
Zubieta, Jon
author_sort DeBurgomaster, Paul
collection PubMed
description The title compound, [V(2)F(2)O(4)(C(10)H(8)N)(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent V(V) atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯F hydrogen bonds.
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spelling pubmed-30078972010-12-30 A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)] DeBurgomaster, Paul Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [V(2)F(2)O(4)(C(10)H(8)N)(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent V(V) atoms are defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the bipyridyl ligand. The crystal packing is stabilized by weak inter­molecular C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007897/ /pubmed/21588507 http://dx.doi.org/10.1107/S1600536810031302 Text en © DeBurgomaster and Zubieta 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
DeBurgomaster, Paul
Zubieta, Jon
A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title_full A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title_fullStr A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title_full_unstemmed A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title_short A binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(V)]
title_sort binuclear vanadium oxyfluoride: di-μ-oxido-bis­[(2,2′-bipyrid­yl)fluorido­oxidovanadium(v)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007897/
https://www.ncbi.nlm.nih.gov/pubmed/21588507
http://dx.doi.org/10.1107/S1600536810031302
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AT zubietajon binuclearvanadiumoxyfluoridedimoxidobis22bipyridylfluoridooxidovanadiumv

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