1-[4-(3,5-Difluoro­benz­yloxy)-2-hy­droxy­phen­yl]ethanone

The title compound, C(15)H(12)F(2)O(3), has been obtained by the reaction of 2,4-dihy­droxy­lacetonephenone, potassium carbonate and 3,5-difluoro­benzyl bromide. The hy­droxy group is involved in an intra­molecular O—H⋯O hydrogen bond in each of the two independent mol­ecules in the asymmetric unit....

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Detalles Bibliográficos
Autores principales: Ma, Ya-Tuan, Zhang, An-Ling, Yuan, Mao-Sen, Gao, Jin-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007899/
https://www.ncbi.nlm.nih.gov/pubmed/21588786
http://dx.doi.org/10.1107/S1600536810033787
Descripción
Sumario:The title compound, C(15)H(12)F(2)O(3), has been obtained by the reaction of 2,4-dihy­droxy­lacetonephenone, potassium carbonate and 3,5-difluoro­benzyl bromide. The hy­droxy group is involved in an intra­molecular O—H⋯O hydrogen bond in each of the two independent mol­ecules in the asymmetric unit. The dihedral angle between the aromatic rings is 0.5 (2)° in one molecule and 1.9 (2)° in the other. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into tetra­meric units aligned perpendicular to b.

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