(1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene

The title compound, C(16)H(22)Cl(2), a derivative of β-himachalene, was semi-synthesized from natural essential oils of Cedrus atlantica. The mol­ecule is built up from two fused six- and seven-membered rings. The six-membered ring has a perfect chair conformation, whereas the seven-membered ring di...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, El Ammari, Lahcen, Berraho, Moha, Lassaba, Esaadia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007900/
https://www.ncbi.nlm.nih.gov/pubmed/21588782
http://dx.doi.org/10.1107/S1600536810034070
Descripción
Sumario:The title compound, C(16)H(22)Cl(2), a derivative of β-himachalene, was semi-synthesized from natural essential oils of Cedrus atlantica. The mol­ecule is built up from two fused six- and seven-membered rings. The six-membered ring has a perfect chair conformation, whereas the seven-membered ring displays a screw boat conformation; the dihedral angle between the rings is 46.48 (9)°.

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