(1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene

The title compound, C(16)H(22)Cl(2), a derivative of β-himachalene, was semi-synthesized from natural essential oils of Cedrus atlantica. The mol­ecule is built up from two fused six- and seven-membered rings. The six-membered ring has a perfect chair conformation, whereas the seven-membered ring di...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, El Ammari, Lahcen, Berraho, Moha, Lassaba, Esaadia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007900/
https://www.ncbi.nlm.nih.gov/pubmed/21588782
http://dx.doi.org/10.1107/S1600536810034070
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author Benharref, Ahmed
El Ammari, Lahcen
Berraho, Moha
Lassaba, Esaadia
author_facet Benharref, Ahmed
El Ammari, Lahcen
Berraho, Moha
Lassaba, Esaadia
author_sort Benharref, Ahmed
collection PubMed
description The title compound, C(16)H(22)Cl(2), a derivative of β-himachalene, was semi-synthesized from natural essential oils of Cedrus atlantica. The mol­ecule is built up from two fused six- and seven-membered rings. The six-membered ring has a perfect chair conformation, whereas the seven-membered ring displays a screw boat conformation; the dihedral angle between the rings is 46.48 (9)°.
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spelling pubmed-30079002010-12-30 (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene Benharref, Ahmed El Ammari, Lahcen Berraho, Moha Lassaba, Esaadia Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(22)Cl(2), a derivative of β-himachalene, was semi-synthesized from natural essential oils of Cedrus atlantica. The mol­ecule is built up from two fused six- and seven-membered rings. The six-membered ring has a perfect chair conformation, whereas the seven-membered ring displays a screw boat conformation; the dihedral angle between the rings is 46.48 (9)°. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007900/ /pubmed/21588782 http://dx.doi.org/10.1107/S1600536810034070 Text en © Benharref et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Benharref, Ahmed
El Ammari, Lahcen
Berraho, Moha
Lassaba, Esaadia
(1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title_full (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title_fullStr (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title_full_unstemmed (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title_short (1S,2S,4R)-3,3-Dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
title_sort (1s,2s,4r)-3,3-dichloro-4,8,12,12-tetra­methyl­tricyclo­[5.5.0.0(2,4)]dodeca-6,8-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007900/
https://www.ncbi.nlm.nih.gov/pubmed/21588782
http://dx.doi.org/10.1107/S1600536810034070
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AT lassabaesaadia 1s2s4r33dichloro481212tetramethyltricyclo550024dodeca68diene

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