Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate

The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol­ecules; each has twofold symmetry with the S atom and the mid-point of the C—C bond of the thio­phene ring located on a twofold rotation axis. In the two mol­ecules, the terminal benzene rings are oriented a...

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Detalles Bibliográficos
Autores principales: Xia, Guang-Ming, Liu, Jing, Li, Zhen, Ji, Mu-Wei, Sun, Guo-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007902/
https://www.ncbi.nlm.nih.gov/pubmed/21588721
http://dx.doi.org/10.1107/S1600536810033210
Descripción
Sumario:The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol­ecules; each has twofold symmetry with the S atom and the mid-point of the C—C bond of the thio­phene ring located on a twofold rotation axis. In the two mol­ecules, the terminal benzene rings are oriented at dihedral angles of 65.8 (3) and 63.5 (3)° with respect to the central thio­phene rings. The meth­oxy­carbonyl group of one mol­ecule is disordered over two positions with site-occupancy factors of 0.277 (12) and 0.723 (12). Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure.

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