Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate

The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol­ecules; each has twofold symmetry with the S atom and the mid-point of the C—C bond of the thio­phene ring located on a twofold rotation axis. In the two mol­ecules, the terminal benzene rings are oriented a...

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Autores principales: Xia, Guang-Ming, Liu, Jing, Li, Zhen, Ji, Mu-Wei, Sun, Guo-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007902/
https://www.ncbi.nlm.nih.gov/pubmed/21588721
http://dx.doi.org/10.1107/S1600536810033210
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author Xia, Guang-Ming
Liu, Jing
Li, Zhen
Ji, Mu-Wei
Sun, Guo-Xin
author_facet Xia, Guang-Ming
Liu, Jing
Li, Zhen
Ji, Mu-Wei
Sun, Guo-Xin
author_sort Xia, Guang-Ming
collection PubMed
description The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol­ecules; each has twofold symmetry with the S atom and the mid-point of the C—C bond of the thio­phene ring located on a twofold rotation axis. In the two mol­ecules, the terminal benzene rings are oriented at dihedral angles of 65.8 (3) and 63.5 (3)° with respect to the central thio­phene rings. The meth­oxy­carbonyl group of one mol­ecule is disordered over two positions with site-occupancy factors of 0.277 (12) and 0.723 (12). Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-30079022010-12-30 Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate Xia, Guang-Ming Liu, Jing Li, Zhen Ji, Mu-Wei Sun, Guo-Xin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(26)H(26)N(2)O(6)S, contains two independent mol­ecules; each has twofold symmetry with the S atom and the mid-point of the C—C bond of the thio­phene ring located on a twofold rotation axis. In the two mol­ecules, the terminal benzene rings are oriented at dihedral angles of 65.8 (3) and 63.5 (3)° with respect to the central thio­phene rings. The meth­oxy­carbonyl group of one mol­ecule is disordered over two positions with site-occupancy factors of 0.277 (12) and 0.723 (12). Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3007902/ /pubmed/21588721 http://dx.doi.org/10.1107/S1600536810033210 Text en © Xia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xia, Guang-Ming
Liu, Jing
Li, Zhen
Ji, Mu-Wei
Sun, Guo-Xin
Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title_full Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title_fullStr Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title_full_unstemmed Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title_short Dimethyl 3,3′-diphenyl-2,2′-[(S)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
title_sort dimethyl 3,3′-diphenyl-2,2′-[(s)-thio­phene-2,5-diylbis(carbonyl­aza­nedi­yl)]dipropano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007902/
https://www.ncbi.nlm.nih.gov/pubmed/21588721
http://dx.doi.org/10.1107/S1600536810033210
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