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catena-Poly[sodium [[tris(3-methylpyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordinated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxylate-O atoms and four pyridine-N atoms. One of the carboxylate ligands bridges the Eu cations, f...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007904/ https://www.ncbi.nlm.nih.gov/pubmed/21588508 http://dx.doi.org/10.1107/S160053681003151X |
Sumario: | In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordinated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxylate-O atoms and four pyridine-N atoms. One of the carboxylate ligands bridges the Eu cations, forming a one-dimensional coordination polymer along the b axis. The Eu—O bond distances lie within the range 2.362 (4)–2.461 (4) Å. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the polymers into a three-dimensional network. |
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