catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]

In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordin­ated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxyl­ate-O atoms and four pyridine-N atoms. One of the carboxyl­ate ligands bridges the Eu cations, f...

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Detalles Bibliográficos
Autor principal: Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007904/
https://www.ncbi.nlm.nih.gov/pubmed/21588508
http://dx.doi.org/10.1107/S160053681003151X
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author Kang, Sung Kwon
author_facet Kang, Sung Kwon
author_sort Kang, Sung Kwon
collection PubMed
description In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordin­ated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxyl­ate-O atoms and four pyridine-N atoms. One of the carboxyl­ate ligands bridges the Eu cations, forming a one-dimensional coordination polymer along the b axis. The Eu—O bond distances lie within the range 2.362 (4)–2.461 (4) Å. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the polymers into a three-dimensional network.
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spelling pubmed-30079042010-12-30 catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate] Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordin­ated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxyl­ate-O atoms and four pyridine-N atoms. One of the carboxyl­ate ligands bridges the Eu cations, forming a one-dimensional coordination polymer along the b axis. The Eu—O bond distances lie within the range 2.362 (4)–2.461 (4) Å. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the polymers into a three-dimensional network. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007904/ /pubmed/21588508 http://dx.doi.org/10.1107/S160053681003151X Text en © Sung Kwon Kang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kang, Sung Kwon
catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title_full catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title_fullStr catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title_full_unstemmed catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title_short catena-Poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
title_sort catena-poly[sodium [[tris(3-methyl­pyridine-2-carboxylato)europate(iii)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007904/
https://www.ncbi.nlm.nih.gov/pubmed/21588508
http://dx.doi.org/10.1107/S160053681003151X
work_keys_str_mv AT kangsungkwon catenapolysodiumtris3methylpyridine2carboxylatoeuropateiiim3methylpyridine2carboxylatotrihydrate

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