Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate

The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy­droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N...

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Detalles Bibliográficos
Autores principales: Bian, Lin, Li, Lianzhi, Zhang, Qingfu, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007907/
https://www.ncbi.nlm.nih.gov/pubmed/21588478
http://dx.doi.org/10.1107/S1600536810030126
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author Bian, Lin
Li, Lianzhi
Zhang, Qingfu
Wang, Daqi
author_facet Bian, Lin
Li, Lianzhi
Zhang, Qingfu
Wang, Daqi
author_sort Bian, Lin
collection PubMed
description The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy­droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa­hedral geometry. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds connect mol­ecules into centrosymmetric dimers. The C atoms of the dimethyl­formamide solvent mol­ecule are disordered over two sites with site-occupancy factors of 0.732 (13) and 0.268 (13).
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spelling pubmed-30079072010-12-30 Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate Bian, Lin Li, Lianzhi Zhang, Qingfu Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy­droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa­hedral geometry. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds connect mol­ecules into centrosymmetric dimers. The C atoms of the dimethyl­formamide solvent mol­ecule are disordered over two sites with site-occupancy factors of 0.732 (13) and 0.268 (13). International Union of Crystallography 2010-08-04 /pmc/articles/PMC3007907/ /pubmed/21588478 http://dx.doi.org/10.1107/S1600536810030126 Text en © Bian et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bian, Lin
Li, Lianzhi
Zhang, Qingfu
Wang, Daqi
Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title_full Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title_fullStr Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title_full_unstemmed Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title_short Oxido{N-[(2-oxido-1-naphthyl-κO)methyl­idene]asparaginato-κ(2) O (1),N (2)}(1,10-phenanthroline-κ(2) N,N′)vanadium(IV) N,N-dimethyl­formamide monosolvate
title_sort oxido{n-[(2-oxido-1-naphthyl-κo)methyl­idene]asparaginato-κ(2) o (1),n (2)}(1,10-phenanthroline-κ(2) n,n′)vanadium(iv) n,n-dimethyl­formamide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007907/
https://www.ncbi.nlm.nih.gov/pubmed/21588478
http://dx.doi.org/10.1107/S1600536810030126
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AT zhangqingfu oxidon2oxido1naphthylkomethylideneasparaginatok2o1n2110phenanthrolinek2nnvanadiumivnndimethylformamidemonosolvate
AT wangdaqi oxidon2oxido1naphthylkomethylideneasparaginatok2o1n2110phenanthrolinek2nnvanadiumivnndimethylformamidemonosolvate

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