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Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN (1)]propanoato(2−)}phenyltin(IV)
In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environ...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007908/ https://www.ncbi.nlm.nih.gov/pubmed/21588519 http://dx.doi.org/10.1107/S1600536810031715 |
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author | Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Affan, Md. Abu |
collection | PubMed |
description | In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environment. Coordinated water molecules link the organotin molecules by forming O—H⋯O hydrogen bonds with both carbonyl and carboxylate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supramolecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N—H⋯Cl hydrogen bonds. |
format | Text |
id | pubmed-3007908 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079082010-12-30 Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN (1)]propanoato(2−)}phenyltin(IV) Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environment. Coordinated water molecules link the organotin molecules by forming O—H⋯O hydrogen bonds with both carbonyl and carboxylate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supramolecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007908/ /pubmed/21588519 http://dx.doi.org/10.1107/S1600536810031715 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN (1)]propanoato(2−)}phenyltin(IV) |
title | Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN
(1)]propanoato(2−)}phenyltin(IV) |
title_full | Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN
(1)]propanoato(2−)}phenyltin(IV) |
title_fullStr | Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN
(1)]propanoato(2−)}phenyltin(IV) |
title_full_unstemmed | Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN
(1)]propanoato(2−)}phenyltin(IV) |
title_short | Aquachlorido{2-[2-(cyclohexylcarbamothioyl-κS)hydrazinylidene-κN
(1)]propanoato(2−)}phenyltin(IV) |
title_sort | aquachlorido{2-[2-(cyclohexylcarbamothioyl-κs)hydrazinylidene-κn
(1)]propanoato(2−)}phenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007908/ https://www.ncbi.nlm.nih.gov/pubmed/21588519 http://dx.doi.org/10.1107/S1600536810031715 |
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