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Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)

In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol­ecule in a distorted octa­hedral coordination environ...

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Autores principales: Affan, Md. Abu, Salam, Md. Abdus, Jusoh, Ismail, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007908/
https://www.ncbi.nlm.nih.gov/pubmed/21588519
http://dx.doi.org/10.1107/S1600536810031715
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author Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol­ecule in a distorted octa­hedral coordination environment. Coordin­ated water mol­ecules link the organotin mol­ecules by forming O—H⋯O hydrogen bonds with both carbonyl and carboxyl­ate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supra­molecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N—H⋯Cl hydrogen bonds.
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spelling pubmed-30079082010-12-30 Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV) Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title organotin compound, [Sn(C(6)H(5))(C(10)H(15)N(3)O(2)S)Cl(H(2)O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water mol­ecule in a distorted octa­hedral coordination environment. Coordin­ated water mol­ecules link the organotin mol­ecules by forming O—H⋯O hydrogen bonds with both carbonyl and carboxyl­ate O atoms, leading to 12-membered {⋯OCO⋯HOH⋯}(2) synthons. This results in the formation of supra­molecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007908/ /pubmed/21588519 http://dx.doi.org/10.1107/S1600536810031715 Text en © Affan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title_full Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title_fullStr Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title_full_unstemmed Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title_short Aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κS)hydrazinyl­idene-κN (1)]propano­ato(2−)}phenyl­tin(IV)
title_sort aqua­chlorido{2-[2-(cyclo­hexyl­carbamo­thioyl-κs)hydrazinyl­idene-κn (1)]propano­ato(2−)}phenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007908/
https://www.ncbi.nlm.nih.gov/pubmed/21588519
http://dx.doi.org/10.1107/S1600536810031715
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