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Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)

In the mononuclear title compound, [Co(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromo­benzoate anion, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule; all...

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Autores principales: Hökelek, Tuncer, Saka, Güner, Tercan, Barış, Öztürkkan, Füreya Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007909/
https://www.ncbi.nlm.nih.gov/pubmed/21588533
http://dx.doi.org/10.1107/S1600536810032630
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author Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the mononuclear title compound, [Co(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromo­benzoate anion, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule; all ligands are monodentate. The four O atoms in the equatorial plane around Co(II) form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-30079092010-12-30 Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II) Hökelek, Tuncer Saka, Güner Tercan, Barış Öztürkkan, Füreya Elif Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Co(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromo­benzoate anion, one diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule; all ligands are monodentate. The four O atoms in the equatorial plane around Co(II) form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007909/ /pubmed/21588533 http://dx.doi.org/10.1107/S1600536810032630 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title_full Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title_fullStr Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title_full_unstemmed Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title_short Diaqua­bis­(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))cobalt(II)
title_sort diaqua­bis­(2-bromo­benzoato-κo)bis­(n,n-diethyl­nicotinamide-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007909/
https://www.ncbi.nlm.nih.gov/pubmed/21588533
http://dx.doi.org/10.1107/S1600536810032630
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