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2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate

In the title salt, C(5)H(6)BrN(2) (+)·C(4)H(3)O(4) (−), the 2-amino-5-bromo­pyridinium cation and hydrogen maleate anion are planar, with maximum deviations from their mean planes of 0.016 (1) and 0.039 (1) Å, respectively. An intra­molecular O—H⋯O hydrogen bond generates an S(7) ring motif in the a...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007912/
https://www.ncbi.nlm.nih.gov/pubmed/21588574
http://dx.doi.org/10.1107/S1600536810030059
Descripción
Sumario:In the title salt, C(5)H(6)BrN(2) (+)·C(4)H(3)O(4) (−), the 2-amino-5-bromo­pyridinium cation and hydrogen maleate anion are planar, with maximum deviations from their mean planes of 0.016 (1) and 0.039 (1) Å, respectively. An intra­molecular O—H⋯O hydrogen bond generates an S(7) ring motif in the anion. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen-bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The motifs are linked into a two-dimensional network parallel to (011) by N—H⋯O and C—H⋯O hydrogen bonds.