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2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate

In the title salt, C(5)H(6)BrN(2) (+)·C(4)H(3)O(4) (−), the 2-amino-5-bromo­pyridinium cation and hydrogen maleate anion are planar, with maximum deviations from their mean planes of 0.016 (1) and 0.039 (1) Å, respectively. An intra­molecular O—H⋯O hydrogen bond generates an S(7) ring motif in the a...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007912/
https://www.ncbi.nlm.nih.gov/pubmed/21588574
http://dx.doi.org/10.1107/S1600536810030059
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(5)H(6)BrN(2) (+)·C(4)H(3)O(4) (−), the 2-amino-5-bromo­pyridinium cation and hydrogen maleate anion are planar, with maximum deviations from their mean planes of 0.016 (1) and 0.039 (1) Å, respectively. An intra­molecular O—H⋯O hydrogen bond generates an S(7) ring motif in the anion. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen-bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The motifs are linked into a two-dimensional network parallel to (011) by N—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-30079122010-12-30 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(6)BrN(2) (+)·C(4)H(3)O(4) (−), the 2-amino-5-bromo­pyridinium cation and hydrogen maleate anion are planar, with maximum deviations from their mean planes of 0.016 (1) and 0.039 (1) Å, respectively. An intra­molecular O—H⋯O hydrogen bond generates an S(7) ring motif in the anion. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen-bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The motifs are linked into a two-dimensional network parallel to (011) by N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3007912/ /pubmed/21588574 http://dx.doi.org/10.1107/S1600536810030059 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title_full 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title_fullStr 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title_full_unstemmed 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title_short 2-Amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
title_sort 2-amino-5-bromo­pyridinium 3-carb­oxy­prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007912/
https://www.ncbi.nlm.nih.gov/pubmed/21588574
http://dx.doi.org/10.1107/S1600536810030059
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