trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)

In the title complex, [Zn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ide (H(2)PIDC(−)) ligands and two water mol­ecules, defi...

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Detalles Bibliográficos
Autores principales: Li, Xia, Du, Ling-Zhi, Wu, Ben-Lai, Zhang, Hong-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007913/
https://www.ncbi.nlm.nih.gov/pubmed/21588565
http://dx.doi.org/10.1107/S1600536810031855
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author Li, Xia
Du, Ling-Zhi
Wu, Ben-Lai
Zhang, Hong-Yun
author_facet Li, Xia
Du, Ling-Zhi
Wu, Ben-Lai
Zhang, Hong-Yun
author_sort Li, Xia
collection PubMed
description In the title complex, [Zn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ide (H(2)PIDC(−)) ligands and two water mol­ecules, defining a distorted octa­hedral environment. The complete solid-state structure can be described as a three-dimensional supra­molecular framework, stabilized by extensive hydrogen-bonding inter­actions involving the coordinated water mol­ecules, uncoordin­ated imidazole N atom, protonated pyridine N and carboxyl­ate O atoms of the H(2)PIDC(−) ligands.
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spelling pubmed-30079132010-12-30 trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II) Li, Xia Du, Ling-Zhi Wu, Ben-Lai Zhang, Hong-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ide (H(2)PIDC(−)) ligands and two water mol­ecules, defining a distorted octa­hedral environment. The complete solid-state structure can be described as a three-dimensional supra­molecular framework, stabilized by extensive hydrogen-bonding inter­actions involving the coordinated water mol­ecules, uncoordin­ated imidazole N atom, protonated pyridine N and carboxyl­ate O atoms of the H(2)PIDC(−) ligands. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007913/ /pubmed/21588565 http://dx.doi.org/10.1107/S1600536810031855 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xia
Du, Ling-Zhi
Wu, Ben-Lai
Zhang, Hong-Yun
trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title_full trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title_fullStr trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title_full_unstemmed trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title_short trans-Diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]zinc(II)
title_sort trans-diaqua­bis­[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1h-imidazol-1-ido-κ(2) n (3),o (4)]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007913/
https://www.ncbi.nlm.nih.gov/pubmed/21588565
http://dx.doi.org/10.1107/S1600536810031855
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AT wubenlai transdiaquabis5carboxy4carboxylato24pyridinio1himidazol1idok2n3o4zincii
AT zhanghongyun transdiaquabis5carboxy4carboxylato24pyridinio1himidazol1idok2n3o4zincii

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