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1′-Acetyl-3-phenyl-6-oxa-4-thia-2-aza­spiro­[bicyclo­[3.2.0]hept-2-ene-7,3′-indolin]-2′-one

In the title indoline compound, C(19)H(14)N(2)O(3)S, the pyrrolidine ring adopts an envelope conformation with the four-connected (spiro) C atom as the flap [displacement = 0.148 (3) Å]. The mean plane formed through the indoline unit is inclined at dihedral angles of 89.92 (16) and 59.54 (12)° with...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Liu, Yang, Zhang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007916/
https://www.ncbi.nlm.nih.gov/pubmed/21588619
http://dx.doi.org/10.1107/S1600536810031016
Descripción
Sumario:In the title indoline compound, C(19)H(14)N(2)O(3)S, the pyrrolidine ring adopts an envelope conformation with the four-connected (spiro) C atom as the flap [displacement = 0.148 (3) Å]. The mean plane formed through the indoline unit is inclined at dihedral angles of 89.92 (16) and 59.54 (12)° with the thia­zole and phenyl rings, respectively; the dihedral angle between the latter rings is 9.55 (14)°. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link neighbouring mol­ecules into inversion dimers, producing R (2) (2)(6) hydrogen-bond ring motifs. Weak inter­molecular C—H⋯π as well as π–π inter­actions [centroid–centroid distance = 3.4041 (15) Å] further consolidate the crystal structure.