Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)

In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta­coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conforma...

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Detalles Bibliográficos
Autores principales: Saleh Salga, Muhammad, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007917/
https://www.ncbi.nlm.nih.gov/pubmed/21588532
http://dx.doi.org/10.1107/S1600536810032563
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author Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Saleh Salga, Muhammad
collection PubMed
description In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta­coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol­ecules are linked together via N—H⋯O and N—H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C—H⋯Cl inter­actions into a three-dimensional network.
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spelling pubmed-30079172010-12-30 Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II) Saleh Salga, Muhammad Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta­coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol­ecules are linked together via N—H⋯O and N—H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C—H⋯Cl inter­actions into a three-dimensional network. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007917/ /pubmed/21588532 http://dx.doi.org/10.1107/S1600536810032563 Text en © Saleh Salga et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title_full Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title_fullStr Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title_full_unstemmed Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title_short Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(II)
title_sort dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth­yl]imino­meth­yl}phenolate)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007917/
https://www.ncbi.nlm.nih.gov/pubmed/21588532
http://dx.doi.org/10.1107/S1600536810032563
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