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(N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV)
The Sn(IV) atom in the title organotin dithiocarbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry i...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007920/ https://www.ncbi.nlm.nih.gov/pubmed/21588504 http://dx.doi.org/10.1107/S1600536810031636 |
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author | Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Abdul Muthalib, Amirah Faizah |
collection | PubMed |
description | The Sn(IV) atom in the title organotin dithiocarbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H⋯Cl and C–H⋯S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H⋯π contacts leads to the formation of supramolecular arrays that stack along the b axis. |
format | Text |
id | pubmed-3007920 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079202010-12-30 (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title organotin dithiocarbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithiocarbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intramolecular C–H⋯Cl and C–H⋯S contacts precludes the Cl and S atoms from forming significant intermolecular contacts. The presence of C–H⋯π contacts leads to the formation of supramolecular arrays that stack along the b axis. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007920/ /pubmed/21588504 http://dx.doi.org/10.1107/S1600536810031636 Text en © Abdul Muthalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward R. T. (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title | (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title_full | (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title_fullStr | (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title_full_unstemmed | (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title_short | (N-Benzyl-N-isopropyldithiocarbamato)chloridodiphenyltin(IV) |
title_sort | (n-benzyl-n-isopropyldithiocarbamato)chloridodiphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007920/ https://www.ncbi.nlm.nih.gov/pubmed/21588504 http://dx.doi.org/10.1107/S1600536810031636 |
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