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(N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)

The Sn(IV) atom in the title organotin dithio­carbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry i...

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Detalles Bibliográficos
Autores principales: Abdul Muthalib, Amirah Faizah, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007920/
https://www.ncbi.nlm.nih.gov/pubmed/21588504
http://dx.doi.org/10.1107/S1600536810031636
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author Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Abdul Muthalib, Amirah Faizah
collection PubMed
description The Sn(IV) atom in the title organotin dithio­carbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H⋯Cl and C–H⋯S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H⋯π contacts leads to the formation of supra­molecular arrays that stack along the b axis.
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spelling pubmed-30079202010-12-30 (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV) Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title organotin dithio­carbamate, [Sn(C(6)H(5))(2)(C(11)H(14)NS(2))Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C(2)ClS(2) donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H⋯Cl and C–H⋯S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H⋯π contacts leads to the formation of supra­molecular arrays that stack along the b axis. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007920/ /pubmed/21588504 http://dx.doi.org/10.1107/S1600536810031636 Text en © Abdul Muthalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward R. T.
(N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title_full (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title_fullStr (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title_full_unstemmed (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title_short (N-Benzyl-N-isopropyl­dithio­carbamato)chloridodiphenyl­tin(IV)
title_sort (n-benzyl-n-isopropyl­dithio­carbamato)chloridodiphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007920/
https://www.ncbi.nlm.nih.gov/pubmed/21588504
http://dx.doi.org/10.1107/S1600536810031636
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