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Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate
In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butylenamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thiazole ring. In the crystal, molecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O interactions. The mo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007924/ https://www.ncbi.nlm.nih.gov/pubmed/21588689 http://dx.doi.org/10.1107/S1600536810030849 |
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author | Baharfar, Robabeh Porahmad, Nasim Vahdat, S. Mohammad |
author_facet | Baharfar, Robabeh Porahmad, Nasim Vahdat, S. Mohammad |
author_sort | Baharfar, Robabeh |
collection | PubMed |
description | In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butylenamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thiazole ring. In the crystal, molecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O interactions. The molecular conformation is stabilized by an intramolecular N—H⋯O hydrogen bond. |
format | Text |
id | pubmed-3007924 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079242010-12-30 Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate Baharfar, Robabeh Porahmad, Nasim Vahdat, S. Mohammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butylenamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thiazole ring. In the crystal, molecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O interactions. The molecular conformation is stabilized by an intramolecular N—H⋯O hydrogen bond. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007924/ /pubmed/21588689 http://dx.doi.org/10.1107/S1600536810030849 Text en © Baharfar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Baharfar, Robabeh Porahmad, Nasim Vahdat, S. Mohammad Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title | Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title_full | Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title_fullStr | Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title_full_unstemmed | Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title_short | Methyl (Z)-3-({5-[(E)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
title_sort | methyl (z)-3-({5-[(e)-(tert-butylamino)methylidene]-4-oxo-4,5-dihydro-1,3-thiazol-2-yl}sulfanyl)prop-2-enoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007924/ https://www.ncbi.nlm.nih.gov/pubmed/21588689 http://dx.doi.org/10.1107/S1600536810030849 |
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