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Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate

In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butyl­enamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thia­zole ring. In the crystal, mol­ecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O inter­actions. The mo...

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Detalles Bibliográficos
Autores principales: Baharfar, Robabeh, Porahmad, Nasim, Vahdat, S. Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007924/
https://www.ncbi.nlm.nih.gov/pubmed/21588689
http://dx.doi.org/10.1107/S1600536810030849
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author Baharfar, Robabeh
Porahmad, Nasim
Vahdat, S. Mohammad
author_facet Baharfar, Robabeh
Porahmad, Nasim
Vahdat, S. Mohammad
author_sort Baharfar, Robabeh
collection PubMed
description In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butyl­enamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thia­zole ring. In the crystal, mol­ecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O inter­actions. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond.
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spelling pubmed-30079242010-12-30 Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate Baharfar, Robabeh Porahmad, Nasim Vahdat, S. Mohammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)N(2)O(3)S(2), the S-vinyl, and tert-butyl­enamine fragments make dihedral angles of 14.19 (2) and 0.85 (2)°, respectively, with the thia­zole ring. In the crystal, mol­ecules are linked into chains with graph-set motifs C(5) along [100] by C—H⋯O inter­actions. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007924/ /pubmed/21588689 http://dx.doi.org/10.1107/S1600536810030849 Text en © Baharfar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baharfar, Robabeh
Porahmad, Nasim
Vahdat, S. Mohammad
Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title_full Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title_fullStr Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title_full_unstemmed Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title_short Methyl (Z)-3-({5-[(E)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
title_sort methyl (z)-3-({5-[(e)-(tert-butyl­amino)­methyl­idene]-4-oxo-4,5-dihydro-1,3-thia­zol-2-yl}sulfan­yl)prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007924/
https://www.ncbi.nlm.nih.gov/pubmed/21588689
http://dx.doi.org/10.1107/S1600536810030849
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AT vahdatsmohammad methylz35etertbutylaminomethylidene4oxo45dihydro13thiazol2ylsulfanylprop2enoate