3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)

The structure determination of the title salt, C(18)H(42)N(4) (2+)·2ClO(4) (−), reveals that protonation has occurred at diagonally opposite amine N atoms. Intra­molecular N—H⋯N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions v...

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Detalles Bibliográficos
Autores principales: Roy, Tapashi G., Hazari, Saroj K. S., Barua, Kanak K., Palit, Provi, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007925/
https://www.ncbi.nlm.nih.gov/pubmed/21588572
http://dx.doi.org/10.1107/S1600536810030217
Descripción
Sumario:The structure determination of the title salt, C(18)H(42)N(4) (2+)·2ClO(4) (−), reveals that protonation has occurred at diagonally opposite amine N atoms. Intra­molecular N—H⋯N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions via N—H⋯O hydrogen bonds into supra­molecular chains propagating along the c axis and weak C—H⋯O inter­actions cross-link the chains.

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