3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)

The structure determination of the title salt, C(18)H(42)N(4) (2+)·2ClO(4) (−), reveals that protonation has occurred at diagonally opposite amine N atoms. Intra­molecular N—H⋯N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions v...

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Detalles Bibliográficos
Autores principales: Roy, Tapashi G., Hazari, Saroj K. S., Barua, Kanak K., Palit, Provi, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007925/
https://www.ncbi.nlm.nih.gov/pubmed/21588572
http://dx.doi.org/10.1107/S1600536810030217
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author Roy, Tapashi G.
Hazari, Saroj K. S.
Barua, Kanak K.
Palit, Provi
Tiekink, Edward R. T.
author_facet Roy, Tapashi G.
Hazari, Saroj K. S.
Barua, Kanak K.
Palit, Provi
Tiekink, Edward R. T.
author_sort Roy, Tapashi G.
collection PubMed
description The structure determination of the title salt, C(18)H(42)N(4) (2+)·2ClO(4) (−), reveals that protonation has occurred at diagonally opposite amine N atoms. Intra­molecular N—H⋯N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions via N—H⋯O hydrogen bonds into supra­molecular chains propagating along the c axis and weak C—H⋯O inter­actions cross-link the chains.
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spelling pubmed-30079252010-12-30 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate) Roy, Tapashi G. Hazari, Saroj K. S. Barua, Kanak K. Palit, Provi Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure determination of the title salt, C(18)H(42)N(4) (2+)·2ClO(4) (−), reveals that protonation has occurred at diagonally opposite amine N atoms. Intra­molecular N—H⋯N hydrogen bonds stabilize the conformation of the dication. In the crystal, the dications are bridged by perchlorate ions via N—H⋯O hydrogen bonds into supra­molecular chains propagating along the c axis and weak C—H⋯O inter­actions cross-link the chains. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3007925/ /pubmed/21588572 http://dx.doi.org/10.1107/S1600536810030217 Text en © Roy et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Roy, Tapashi G.
Hazari, Saroj K. S.
Barua, Kanak K.
Palit, Provi
Tiekink, Edward R. T.
3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title_full 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title_fullStr 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title_full_unstemmed 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title_short 3,10-C-meso-3,5,7,7,10,12,14,14-Octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
title_sort 3,10-c-meso-3,5,7,7,10,12,14,14-octa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane bis­(perchlorate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007925/
https://www.ncbi.nlm.nih.gov/pubmed/21588572
http://dx.doi.org/10.1107/S1600536810030217
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