Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate

In the title compound, [Co(C(19)H(13)ClN(3)O)(2)]NO(3)·2CH(3)OH, the central Co(III) atom in the cation is surrounded by two tridentate ligands in a distorted octa­hedral fashion by four N and two O atoms. Classical O—H⋯O hydrogen bonds link both methanol solvent mol­ecules with the nitrate anion....

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Detalles Bibliográficos
Autores principales: Wu, Genhua, Ye, Hui, Wu, Dayu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007928/
https://www.ncbi.nlm.nih.gov/pubmed/21588525
http://dx.doi.org/10.1107/S1600536810032241
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author Wu, Genhua
Ye, Hui
Wu, Dayu
author_facet Wu, Genhua
Ye, Hui
Wu, Dayu
author_sort Wu, Genhua
collection PubMed
description In the title compound, [Co(C(19)H(13)ClN(3)O)(2)]NO(3)·2CH(3)OH, the central Co(III) atom in the cation is surrounded by two tridentate ligands in a distorted octa­hedral fashion by four N and two O atoms. Classical O—H⋯O hydrogen bonds link both methanol solvent mol­ecules with the nitrate anion.
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spelling pubmed-30079282010-12-30 Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate Wu, Genhua Ye, Hui Wu, Dayu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(19)H(13)ClN(3)O)(2)]NO(3)·2CH(3)OH, the central Co(III) atom in the cation is surrounded by two tridentate ligands in a distorted octa­hedral fashion by four N and two O atoms. Classical O—H⋯O hydrogen bonds link both methanol solvent mol­ecules with the nitrate anion. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007928/ /pubmed/21588525 http://dx.doi.org/10.1107/S1600536810032241 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Genhua
Ye, Hui
Wu, Dayu
Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title_full Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title_fullStr Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title_full_unstemmed Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title_short Bis{4-chloro-N′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) N′,O}cobalt(III) nitrate methanol disolvate
title_sort bis{4-chloro-n′-[phen­yl(2-pyrid­yl)methyl­idene]benzohydrazidato-κ(2) n′,o}cobalt(iii) nitrate methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007928/
https://www.ncbi.nlm.nih.gov/pubmed/21588525
http://dx.doi.org/10.1107/S1600536810032241
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AT wudayu bis4chloronphenyl2pyridylmethylidenebenzohydrazidatok2nocobaltiiinitratemethanoldisolvate

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