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Bis(acridine-κN)dibromidoplatinum(II)

In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex...

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Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007929/
https://www.ncbi.nlm.nih.gov/pubmed/21588540
http://dx.doi.org/10.1107/S160053681003309X
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PtN(2)Br(2) unit is exactly planar. The dihedral angle between the PtN(2)Br(2) unit and acridine ligand is 78.98 (9)°. In the crystal structure, the complex mol­ecules are arranged in two distinct chains along [110] and [[Image: see text]10]. In the chains, inter­molecular π–π inter­actions between the pyridyl and benzene rings connect the complex mol­ecules, with a centroid–centroid distance of 3.631 (4) Å.
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spelling pubmed-30079292010-12-30 Bis(acridine-κN)dibromidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PtN(2)Br(2) unit is exactly planar. The dihedral angle between the PtN(2)Br(2) unit and acridine ligand is 78.98 (9)°. In the crystal structure, the complex mol­ecules are arranged in two distinct chains along [110] and [[Image: see text]10]. In the chains, inter­molecular π–π inter­actions between the pyridyl and benzene rings connect the complex mol­ecules, with a centroid–centroid distance of 3.631 (4) Å. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007929/ /pubmed/21588540 http://dx.doi.org/10.1107/S160053681003309X Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(acridine-κN)dibromidoplatinum(II)
title Bis(acridine-κN)dibromidoplatinum(II)
title_full Bis(acridine-κN)dibromidoplatinum(II)
title_fullStr Bis(acridine-κN)dibromidoplatinum(II)
title_full_unstemmed Bis(acridine-κN)dibromidoplatinum(II)
title_short Bis(acridine-κN)dibromidoplatinum(II)
title_sort bis(acridine-κn)dibromidoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007929/
https://www.ncbi.nlm.nih.gov/pubmed/21588540
http://dx.doi.org/10.1107/S160053681003309X
work_keys_str_mv AT hakwang bisacridinekndibromidoplatinumii