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Bis(acridine-κN)dibromidoplatinum(II)
In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007929/ https://www.ncbi.nlm.nih.gov/pubmed/21588540 http://dx.doi.org/10.1107/S160053681003309X |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PtN(2)Br(2) unit is exactly planar. The dihedral angle between the PtN(2)Br(2) unit and acridine ligand is 78.98 (9)°. In the crystal structure, the complex molecules are arranged in two distinct chains along [110] and [[Image: see text]10]. In the chains, intermolecular π–π interactions between the pyridyl and benzene rings connect the complex molecules, with a centroid–centroid distance of 3.631 (4) Å. |
format | Text |
id | pubmed-3007929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079292010-12-30 Bis(acridine-κN)dibromidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtBr(2)(C(13)H(9)N)(2)], the Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms from two acridine ligands and two Br atoms. The Pt atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PtN(2)Br(2) unit is exactly planar. The dihedral angle between the PtN(2)Br(2) unit and acridine ligand is 78.98 (9)°. In the crystal structure, the complex molecules are arranged in two distinct chains along [110] and [[Image: see text]10]. In the chains, intermolecular π–π interactions between the pyridyl and benzene rings connect the complex molecules, with a centroid–centroid distance of 3.631 (4) Å. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007929/ /pubmed/21588540 http://dx.doi.org/10.1107/S160053681003309X Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Bis(acridine-κN)dibromidoplatinum(II) |
title | Bis(acridine-κN)dibromidoplatinum(II) |
title_full | Bis(acridine-κN)dibromidoplatinum(II) |
title_fullStr | Bis(acridine-κN)dibromidoplatinum(II) |
title_full_unstemmed | Bis(acridine-κN)dibromidoplatinum(II) |
title_short | Bis(acridine-κN)dibromidoplatinum(II) |
title_sort | bis(acridine-κn)dibromidoplatinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007929/ https://www.ncbi.nlm.nih.gov/pubmed/21588540 http://dx.doi.org/10.1107/S160053681003309X |
work_keys_str_mv | AT hakwang bisacridinekndibromidoplatinumii |