[Amino­(iminio)meth­yl]phospho­nate

The title compound, CH(5)N(2)O(3)P, exists as a zwitterion. The N atom of the imino group is protonated and the phospho­nic acid group is deprotonated. The mol­ecular geometry about the central C atom of this zwitterionic species was found to be strictly planar with the sum of the three angles about...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Ting-Hai, Zhuang, Wei, Wei, Wei, Yang, Yong-Bing, Chen, Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007934/
https://www.ncbi.nlm.nih.gov/pubmed/21588672
http://dx.doi.org/10.1107/S1600536810032083
_version_ 1782194462657609728
author Yang, Ting-Hai
Zhuang, Wei
Wei, Wei
Yang, Yong-Bing
Chen, Qiang
author_facet Yang, Ting-Hai
Zhuang, Wei
Wei, Wei
Yang, Yong-Bing
Chen, Qiang
author_sort Yang, Ting-Hai
collection PubMed
description The title compound, CH(5)N(2)O(3)P, exists as a zwitterion. The N atom of the imino group is protonated and the phospho­nic acid group is deprotonated. The mol­ecular geometry about the central C atom of this zwitterionic species was found to be strictly planar with the sum of the three angles about C being precisely 360°. In the crystal, the mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional supra­molecular network structure.
format Text
id pubmed-3007934
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079342010-12-30 [Amino­(iminio)meth­yl]phospho­nate Yang, Ting-Hai Zhuang, Wei Wei, Wei Yang, Yong-Bing Chen, Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, CH(5)N(2)O(3)P, exists as a zwitterion. The N atom of the imino group is protonated and the phospho­nic acid group is deprotonated. The mol­ecular geometry about the central C atom of this zwitterionic species was found to be strictly planar with the sum of the three angles about C being precisely 360°. In the crystal, the mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional supra­molecular network structure. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007934/ /pubmed/21588672 http://dx.doi.org/10.1107/S1600536810032083 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Ting-Hai
Zhuang, Wei
Wei, Wei
Yang, Yong-Bing
Chen, Qiang
[Amino­(iminio)meth­yl]phospho­nate
title [Amino­(iminio)meth­yl]phospho­nate
title_full [Amino­(iminio)meth­yl]phospho­nate
title_fullStr [Amino­(iminio)meth­yl]phospho­nate
title_full_unstemmed [Amino­(iminio)meth­yl]phospho­nate
title_short [Amino­(iminio)meth­yl]phospho­nate
title_sort [amino­(iminio)meth­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007934/
https://www.ncbi.nlm.nih.gov/pubmed/21588672
http://dx.doi.org/10.1107/S1600536810032083
work_keys_str_mv AT yangtinghai aminoiminiomethylphosphonate
AT zhuangwei aminoiminiomethylphosphonate
AT weiwei aminoiminiomethylphosphonate
AT yangyongbing aminoiminiomethylphosphonate
AT chenqiang aminoiminiomethylphosphonate

Ejemplares similares