Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)

In the title compound, [Co(II)Cl(2)(C(6)H(10)N(2))(2)], a pair of 3,4,5-trimethyl­pyrazoles act as monodentate ligands. Two Cl(−) anions are also bonded directly to the Co(II) atom, which has a CoN(2)Cl(2) chromophore in a slightly distorted tetra­hedral geometry. The two mol­ecules in the asymmetri...

Descripción completa

Detalles Bibliográficos
Autores principales: Lyubartseva, Ganna, Parkin, Sean
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007936/
https://www.ncbi.nlm.nih.gov/pubmed/21588534
http://dx.doi.org/10.1107/S160053681003254X
_version_ 1782194463120031744
author Lyubartseva, Ganna
Parkin, Sean
author_facet Lyubartseva, Ganna
Parkin, Sean
author_sort Lyubartseva, Ganna
collection PubMed
description In the title compound, [Co(II)Cl(2)(C(6)H(10)N(2))(2)], a pair of 3,4,5-trimethyl­pyrazoles act as monodentate ligands. Two Cl(−) anions are also bonded directly to the Co(II) atom, which has a CoN(2)Cl(2) chromophore in a slightly distorted tetra­hedral geometry. The two mol­ecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N—H⋯Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis.
format Text
id pubmed-3007936
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079362010-12-30 Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II) Lyubartseva, Ganna Parkin, Sean Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(II)Cl(2)(C(6)H(10)N(2))(2)], a pair of 3,4,5-trimethyl­pyrazoles act as monodentate ligands. Two Cl(−) anions are also bonded directly to the Co(II) atom, which has a CoN(2)Cl(2) chromophore in a slightly distorted tetra­hedral geometry. The two mol­ecules in the asymmetric unit are related by an approximate twofold rotation roughly parallel to the a axis. The amino H atom in the pyrazole ring participates in weak N—H⋯Cl hydrogen bonds to form chains that propagate roughly parallel to the c axis. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007936/ /pubmed/21588534 http://dx.doi.org/10.1107/S160053681003254X Text en © Lyubartseva and Parkin 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyubartseva, Ganna
Parkin, Sean
Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title_full Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title_fullStr Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title_full_unstemmed Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title_short Dichloridobis(3,4,5-trimethyl-1H-pyrazole-κN (2))cobalt(II)
title_sort dichloridobis(3,4,5-trimethyl-1h-pyrazole-κn (2))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007936/
https://www.ncbi.nlm.nih.gov/pubmed/21588534
http://dx.doi.org/10.1107/S160053681003254X
work_keys_str_mv AT lyubartsevaganna dichloridobis345trimethyl1hpyrazolekn2cobaltii
AT parkinsean dichloridobis345trimethyl1hpyrazolekn2cobaltii

Ejemplares similares