trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)

In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2))(2)(H(2)O)(2)], the Ni(II )atom, located on an inversion center, is six-coordinated in a distorted octa­hedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyrid­yl)acetate ligands and two aqua ligands. The mol­ecules...

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Detalles Bibliográficos
Autores principales: Zhou, Hong, Zhao, Lei, Huang, Rong, Li, Hao-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007937/
https://www.ncbi.nlm.nih.gov/pubmed/21588490
http://dx.doi.org/10.1107/S1600536810030904
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author Zhou, Hong
Zhao, Lei
Huang, Rong
Li, Hao-Liang
author_facet Zhou, Hong
Zhao, Lei
Huang, Rong
Li, Hao-Liang
author_sort Zhou, Hong
collection PubMed
description In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2))(2)(H(2)O)(2)], the Ni(II )atom, located on an inversion center, is six-coordinated in a distorted octa­hedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyrid­yl)acetate ligands and two aqua ligands. The mol­ecules form a three-dimensional framework by O—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.506 (3) Å.
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spelling pubmed-30079372010-12-30 trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II) Zhou, Hong Zhao, Lei Huang, Rong Li, Hao-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2))(2)(H(2)O)(2)], the Ni(II )atom, located on an inversion center, is six-coordinated in a distorted octa­hedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyrid­yl)acetate ligands and two aqua ligands. The mol­ecules form a three-dimensional framework by O—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.506 (3) Å. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007937/ /pubmed/21588490 http://dx.doi.org/10.1107/S1600536810030904 Text en © Zhou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Hong
Zhao, Lei
Huang, Rong
Li, Hao-Liang
trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title_full trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title_fullStr trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title_full_unstemmed trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title_short trans-Diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) N,O]nickel(II)
title_sort trans-diaqua­bis­[2-(2-pyrid­yl)acetato-κ(2) n,o]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007937/
https://www.ncbi.nlm.nih.gov/pubmed/21588490
http://dx.doi.org/10.1107/S1600536810030904
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AT lihaoliang transdiaquabis22pyridylacetatok2nonickelii

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