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(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)

In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [max...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/
https://www.ncbi.nlm.nih.gov/pubmed/21588501
http://dx.doi.org/10.1107/S1600536810031387
Descripción
Sumario:In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex mol­ecules are arranged in a V-shaped packing pattern along the c axis and linked by inter­molecular C—H⋯O contacts into supra­molecular chains. There are also several inter­molecular π–π inter­actions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å.