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(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [max...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/ https://www.ncbi.nlm.nih.gov/pubmed/21588501 http://dx.doi.org/10.1107/S1600536810031387 |
Sumario: | In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex molecules are arranged in a V-shaped packing pattern along the c axis and linked by intermolecular C—H⋯O contacts into supramolecular chains. There are also several intermolecular π–π interactions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å. |
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