Cargando…

(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)

In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [max...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/
https://www.ncbi.nlm.nih.gov/pubmed/21588501
http://dx.doi.org/10.1107/S1600536810031387
_version_ 1782194464299679744
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex mol­ecules are arranged in a V-shaped packing pattern along the c axis and linked by inter­molecular C—H⋯O contacts into supra­molecular chains. There are also several inter­molecular π–π inter­actions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å.
format Text
id pubmed-3007941
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079412010-12-30 (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex mol­ecules are arranged in a V-shaped packing pattern along the c axis and linked by inter­molecular C—H⋯O contacts into supra­molecular chains. There are also several inter­molecular π–π inter­actions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007941/ /pubmed/21588501 http://dx.doi.org/10.1107/S1600536810031387 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title_full (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title_fullStr (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title_full_unstemmed (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title_short (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
title_sort (acridine-κn)(dimethyl sulfoxide-κs)diiodidoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/
https://www.ncbi.nlm.nih.gov/pubmed/21588501
http://dx.doi.org/10.1107/S1600536810031387
work_keys_str_mv AT hakwang acridinekndimethylsulfoxideksdiiodidoplatinumii