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(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [max...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/ https://www.ncbi.nlm.nih.gov/pubmed/21588501 http://dx.doi.org/10.1107/S1600536810031387 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex molecules are arranged in a V-shaped packing pattern along the c axis and linked by intermolecular C—H⋯O contacts into supramolecular chains. There are also several intermolecular π–π interactions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å. |
format | Text |
id | pubmed-3007941 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079412010-12-30 (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex molecules are arranged in a V-shaped packing pattern along the c axis and linked by intermolecular C—H⋯O contacts into supramolecular chains. There are also several intermolecular π–π interactions between the six-membered rings, with a shortest ring centroid–centroid distance of 3.804 (5) Å. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007941/ /pubmed/21588501 http://dx.doi.org/10.1107/S1600536810031387 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title | (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title_full | (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title_fullStr | (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title_full_unstemmed | (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title_short | (Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II) |
title_sort | (acridine-κn)(dimethyl sulfoxide-κs)diiodidoplatinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007941/ https://www.ncbi.nlm.nih.gov/pubmed/21588501 http://dx.doi.org/10.1107/S1600536810031387 |
work_keys_str_mv | AT hakwang acridinekndimethylsulfoxideksdiiodidoplatinumii |