μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate

The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2′-[o-phenylene­bis(nitrilo­methylidyne)]diphenolate (salphen) dimers, one methanol mol­ecule and two H(2)O mol­ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the...

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Detalles Bibliográficos
Autores principales: Yan, Jia-Hao, Shen, Xiao-Ping, Zhou, Hu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007942/
https://www.ncbi.nlm.nih.gov/pubmed/21588506
http://dx.doi.org/10.1107/S1600536810031533
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author Yan, Jia-Hao
Shen, Xiao-Ping
Zhou, Hu
author_facet Yan, Jia-Hao
Shen, Xiao-Ping
Zhou, Hu
author_sort Yan, Jia-Hao
collection PubMed
description The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2′-[o-phenylene­bis(nitrilo­methylidyne)]diphenolate (salphen) dimers, one methanol mol­ecule and two H(2)O mol­ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the salphen ligand and one bridging O atom, shows a five-coordinate square-pyramidal geometry. One of the two solvent water mol­ecules is disordered over three positions with occupancies of 0.44 (1), 0.37 (1) and 0.19 (1).
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spelling pubmed-30079422010-12-30 μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate Yan, Jia-Hao Shen, Xiao-Ping Zhou, Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2′-[o-phenylene­bis(nitrilo­methylidyne)]diphenolate (salphen) dimers, one methanol mol­ecule and two H(2)O mol­ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the salphen ligand and one bridging O atom, shows a five-coordinate square-pyramidal geometry. One of the two solvent water mol­ecules is disordered over three positions with occupancies of 0.44 (1), 0.37 (1) and 0.19 (1). International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007942/ /pubmed/21588506 http://dx.doi.org/10.1107/S1600536810031533 Text en © Yan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yan, Jia-Hao
Shen, Xiao-Ping
Zhou, Hu
μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title_full μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title_fullStr μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title_full_unstemmed μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title_short μ-Oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate
title_sort μ-oxido-bis­({2,2′-[o-phenylenebis(nitrilo­methylidyne)]diphenolato}iron(iii)) methanol monosolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007942/
https://www.ncbi.nlm.nih.gov/pubmed/21588506
http://dx.doi.org/10.1107/S1600536810031533
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