Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)

In the centrosymmetric title mol­ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu—Cu = 2.6540 (4) Å]. The distorted octa­hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl­pyrimidin-2-amine ligand: an intra...

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Detalles Bibliográficos
Autores principales: Aiyub, Zaharah, Badaruddin, Edura, Abdullah, Zanariah, Fairuz, Zainal A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007943/
https://www.ncbi.nlm.nih.gov/pubmed/21588567
http://dx.doi.org/10.1107/S1600536810034033
Descripción
Sumario:In the centrosymmetric title mol­ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu—Cu = 2.6540 (4) Å]. The distorted octa­hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl­pyrimidin-2-amine ligand: an intra­molecular N—H⋯O hydrogen links its N—H group to an acetate carboxyl­ate O atom. In the crystal, C—H⋯O inter­actions link the mol­ecules into a supra­molecular chain along the b axis.

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