Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)

In the centrosymmetric title mol­ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu—Cu = 2.6540 (4) Å]. The distorted octa­hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl­pyrimidin-2-amine ligand: an intra...

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Autores principales: Aiyub, Zaharah, Badaruddin, Edura, Abdullah, Zanariah, Fairuz, Zainal A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007943/
https://www.ncbi.nlm.nih.gov/pubmed/21588567
http://dx.doi.org/10.1107/S1600536810034033
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author Aiyub, Zaharah
Badaruddin, Edura
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Aiyub, Zaharah
Badaruddin, Edura
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Aiyub, Zaharah
collection PubMed
description In the centrosymmetric title mol­ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu—Cu = 2.6540 (4) Å]. The distorted octa­hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl­pyrimidin-2-amine ligand: an intra­molecular N—H⋯O hydrogen links its N—H group to an acetate carboxyl­ate O atom. In the crystal, C—H⋯O inter­actions link the mol­ecules into a supra­molecular chain along the b axis.
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spelling pubmed-30079432010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu) Aiyub, Zaharah Badaruddin, Edura Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title mol­ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu—Cu = 2.6540 (4) Å]. The distorted octa­hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl­pyrimidin-2-amine ligand: an intra­molecular N—H⋯O hydrogen links its N—H group to an acetate carboxyl­ate O atom. In the crystal, C—H⋯O inter­actions link the mol­ecules into a supra­molecular chain along the b axis. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007943/ /pubmed/21588567 http://dx.doi.org/10.1107/S1600536810034033 Text en © Aiyub et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aiyub, Zaharah
Badaruddin, Edura
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title_full Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title_fullStr Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title_full_unstemmed Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title_short Tetra-μ-acetato-κ(8) O:O′-bis­[(N-ethyl­pyrimidin-2-amine)­copper(II)](Cu—Cu)
title_sort tetra-μ-acetato-κ(8) o:o′-bis­[(n-ethyl­pyrimidin-2-amine)­copper(ii)](cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007943/
https://www.ncbi.nlm.nih.gov/pubmed/21588567
http://dx.doi.org/10.1107/S1600536810034033
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